1oxidation
loses electrons, becomes more postitive
- is the reducing agent
2reduction
gains electrons, becomes more negative
- is the oxidizing agent
4cathode
cite of reduction
5anode ---> cathode
direction of electron flow
6anode ---> cathode
direction of positive ion flow
7cathode---> anode
direction of negative ion flow
8salt bridge
maintains charge neutrality
9active, least
most ___ element replaces ___ active element
10taker
the more positive the E* value, the more readily the reactant will act as a ____
bc it is the oxidizing agent= gets reduced= gaining/taking electrons
11giver
the more negative the E* value, the more readily the product will act as a ____
12ΔG < 0, negative
Ecell > 0, positive
signs of ΔG and Ecell for spontaneous reactions
13covalent bond
each atom contributes one electron to the shared pair
14coordinate covalent bond
one atom donates both electrons to the shared pair; one atom acts as the sole electron donor
15complex ion
consists of a central metal ion covalently bonded to two or more anions or molecules called ligands
16ligands
molecule or anions bonded to central metal ion; must have at least one unshared pair of valence electrons
17donor atom
the atom in the lignand that is bound directly to the metal atom (the atom givin up electrons)
18coordination number
number of donor atoms surrounding the central metal atom in a complex ion
19monodentate
1 donor atom
21polydentate
more than two donor atoms
22stereoisomers
compounds in which ligands are arranged differently around the central atom; have distinctly different physical and chemical properties
there are two types: geometric and optical
23geometrical isomers
stereoisomers that cannot be interconverted w/o breaking chemical bonds; come in pairs: cis and trans
24cis
two particular atoms are adjacent to each other
25trans
atoms are on the opposite sides in the structural formula
26optical isomers
nonsuperimposable mirror images; two objects cannot be rotated or placed on top of each other so that all points match
27stronger oxidizing agent
high ionization energy(takes more energy to remove electrons bc they're held tighter together) =
28reducing agent
low electronegativity(takes less energy to remove electrons) =