chem 142 exam 4

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1
oxidation
loses electrons, becomes more postitive
- is the reducing agent
2
reduction
gains electrons, becomes more negative
- is the oxidizing agent
3
anode
cite of oxidation
4
cathode
cite of reduction
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anode ---> cathode
direction of electron flow
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anode ---> cathode
direction of positive ion flow
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cathode---> anode
direction of negative ion flow
8
salt bridge
maintains charge neutrality
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active, least
most ___ element replaces ___ active element
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taker
the more positive the E* value, the more readily the reactant will act as a ____
bc it is the oxidizing agent= gets reduced= gaining/taking electrons
11
giver
the more negative the E* value, the more readily the product will act as a ____
12
ΔG < 0, negative
Ecell > 0, positive
signs of ΔG and Ecell for spontaneous reactions
13
covalent bond
each atom contributes one electron to the shared pair
14
coordinate covalent bond
one atom donates both electrons to the shared pair; one atom acts as the sole electron donor
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complex ion
consists of a central metal ion covalently bonded to two or more anions or molecules called ligands
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ligands
molecule or anions bonded to central metal ion; must have at least one unshared pair of valence electrons
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donor atom
the atom in the lignand that is bound directly to the metal atom (the atom givin up electrons)
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coordination number
number of donor atoms surrounding the central metal atom in a complex ion
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monodentate
1 donor atom
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bidentate
2 donor atoms
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polydentate
more than two donor atoms
22
stereoisomers
compounds in which ligands are arranged differently around the central atom; have distinctly different physical and chemical properties
there are two types: geometric and optical
23
geometrical isomers
stereoisomers that cannot be interconverted w/o breaking chemical bonds; come in pairs: cis and trans
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cis
two particular atoms are adjacent to each other
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trans
atoms are on the opposite sides in the structural formula
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optical isomers
nonsuperimposable mirror images; two objects cannot be rotated or placed on top of each other so that all points match
27
stronger oxidizing agent
high ionization energy(takes more energy to remove electrons bc they're held tighter together) =
28
reducing agent
low electronegativity(takes less energy to remove electrons) =
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