chem 142 exam 4

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1
oxidation
loses electrons, becomes more postitive
- is the reducing agent
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reduction
gains electrons, becomes more negative
- is the oxidizing agent
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anode
cite of oxidation
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cathode
cite of reduction
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anode ---> cathode
direction of electron flow
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anode ---> cathode
direction of positive ion flow
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cathode---> anode
direction of negative ion flow
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salt bridge
maintains charge neutrality
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active, least
most ___ element replaces ___ active element
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taker
the more positive the E* value, the more readily the reactant will act as a ____
bc it is the oxidizing agent= gets reduced= gaining/taking electrons
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giver
the more negative the E* value, the more readily the product will act as a ____
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ΔG < 0, negative
Ecell > 0, positive
signs of ΔG and Ecell for spontaneous reactions
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covalent bond
each atom contributes one electron to the shared pair
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coordinate covalent bond
one atom donates both electrons to the shared pair; one atom acts as the sole electron donor
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complex ion
consists of a central metal ion covalently bonded to two or more anions or molecules called ligands
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ligands
molecule or anions bonded to central metal ion; must have at least one unshared pair of valence electrons
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donor atom
the atom in the lignand that is bound directly to the metal atom (the atom givin up electrons)
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coordination number
number of donor atoms surrounding the central metal atom in a complex ion
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monodentate
1 donor atom
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bidentate
2 donor atoms
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polydentate
more than two donor atoms
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stereoisomers
compounds in which ligands are arranged differently around the central atom; have distinctly different physical and chemical properties
there are two types: geometric and optical
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geometrical isomers
stereoisomers that cannot be interconverted w/o breaking chemical bonds; come in pairs: cis and trans
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cis
two particular atoms are adjacent to each other
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trans
atoms are on the opposite sides in the structural formula
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optical isomers
nonsuperimposable mirror images; two objects cannot be rotated or placed on top of each other so that all points match
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stronger oxidizing agent
high ionization energy(takes more energy to remove electrons bc they're held tighter together) =
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reducing agent
low electronegativity(takes less energy to remove electrons) =
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