1mass number (A)
number of proton +number of neutrons= number of nucleons
2atomic number (z)
z=number of proton
3isotopes,isobars,isotones,isoelectronic species
isotopes=same atomic number different atomic mass isobars=different atomic number same atomic mass isotone=different elements having same number of neutrons isoelectronic species=can be atom molecules or ions with same number of electron
4velocity,wave number
c=wavelength*frequency
5electromagnetic spectrum wavelength increasing order
Gamma rays<x-rays<Ultraviolet<visible <infrared<microwave<radio wave
6planck theory
E=nh*frequency=nhc/wavelength
7photoelectric effect
h*frequency=Wo+K.E
8threshold frequency Wo
Wo=h*frequency°=hc/wavelength°
9angular momentum quantization
mvr=nh/2π
10bohr frequency
frequency=∆E/h
11radius of bohr orbit
rn=0.529×n^2/z amstrong
12velocity of an electron in an orbit
vn=2.19×10^6 Z/n m/s
13time period and frequency
time period T =2πr/V T proportional to n^3/Z^2 frequency proportional to Z^2/n^3
14Energy
E=2π^2me^4/n^2h^2 = -21.8*10^-19Z^2/n^2 J/atom =-13.6Z^2/n^2 ev/atom =-1312Z^2/n^2 kJ/mole =-313.6Z^2/n^2 kcal/mol
15total energy potential energy Kinetic energy
total energy=-13.6 Z^2/n^2 ev/atom K.E= 13.6 Z^2/n^2 ev/atom P.E=-27.2 Z^2/n^2 ev/atom
16number of revolutions
vn/2πrn
17lamda(max) , lamda (min)
lamda(max)=n^2(n+1)^2/(2n+1)RZ^2 ,lamda(min) =n^2/RZ^2
18rydberg formula
lamda=(9.12*10^-6/z^2)*n1^2n2^2/n2^2-n1^2 cm frequency= 3.29×10^15(1/n1^2-1/n2^2)s^-1
19number of spectral lines produced
((n2-n1)(n2-n1+1))/2
20wavelength in terms of momentum ke and qv
lamda=h/mv =h/√(2mke). =h/√(2mqV)
21number of ade by an electron in nth orbit
n
22Heisenberg uncertainty principle
∆x.∆p= h/4π (h/4π=5.25*10^-35)
23quantum numbers
principle quantum number(n) : determine energy and average distance of an electron from the nucleus (size) , azimuthal quantum number(l): possible value 0 to n-1determines angular momentum of the electron gives subshell of electron is located L=(h/2π)*√(l(l+1), magnetic quantum number (m): different orengtal possible value -l o zero to +l (2l+1) value maximum electron in subshell=2(2l+1), spin quantum number (s) denote spin moton of electron can have -1/2 or +1/2 values spin magnetic moment=√(n(n+2)) (n is number of unpaired electron)
24no of subshell in nth shell ,no of orbitals in nth shell,no of electron in nth shell,no of orbitals in a subshell of electron in a subshell , no of radial nodes ,no of angular nodes , no of of l values,no of m values,No of s values
n,n^2,2n^2,2l+1,4l+2,n-l-1,l,no of subshells ,no of of orbitals ,no.electrons