1defineed as the maximum mass of a substance that can be dissolved in a fixed mass of a solvent at a given temperature
solubility
2a substance will have a different solubility in different solvents depending on what?
polarity of both substance and the solvent
3alcohols, amines, acids, esters, ketones, and aldehydes
water
45% NaHCO3
carboxylic acids
55% NaOH
carboxylic acids and phenols
7most organic molecules
diethyl ether
8these are usually soluble in organic solvents
organic molecules
9it is held together by intermolecular forces
crystalline matrix
10this is the temperature range over which the solid melts to become a liquid
melting point
11the transition between the solid and the liquid is so sharp for small samples of pure substance that meltiing poits can be measured to
+1oC
12characterstics of molecule can be used to determine
identity and purity
13four factors influencing melting point
-molecular symmetry
-molecular polarity
h-bondng
-molecular weight
14mp of pentane
130 degree celsius
15mp of 2,2-dimethylpropane
-17 degree celsius
16h- bonds of benzoic acid
2
17h-bonds of benzoic alcohol
1
18the ability of molecules to pack together tightly influences what?
intermolecular interactions and melting point
19tighter packing increases what?
melting point
20have sharp melting point whereas mixtures melt with a broad temperature range
pure crystalline solids
21even chains pack tighter than odd
true
22molecules with this shape have unusually high melting points
spherical shapes
23what device do we use to measure melting point?
electrothermal melt-point tester
24what properties are melting and boiling points?
physical
25if boiling does occur under these conditions, what will occur?
explosive violence
26these can be used to identify the unknown drugs
melting and boiling point
27the difference in boiling point informs the difference in
molecular structure
28an antiseptic that has boilin gpoint higher than ether that was used as general anesthetic
phenol
29measure of how much the speed of light is reeduced inside the medium
index of refraction
30often used to identify a particular substance, confirm its purity, or measure its concentration
refractive index