exercise 5

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1
defineed as the maximum mass of a substance that can be dissolved in a fixed mass of a solvent at a given temperature
solubility
2
a substance will have a different solubility in different solvents depending on what?
polarity of both substance and the solvent
3
alcohols, amines, acids, esters, ketones, and aldehydes
water
4
5% NaHCO3
carboxylic acids
5
5% NaOH
carboxylic acids and phenols
6
5% HCl
amines
7
most organic molecules
diethyl ether
8
these are usually soluble in organic solvents
organic molecules
9
it is held together by intermolecular forces
crystalline matrix
10
this is the temperature range over which the solid melts to become a liquid
melting point
11
the transition between the solid and the liquid is so sharp for small samples of pure substance that meltiing poits can be measured to
+1oC
12
characterstics of molecule can be used to determine
identity and purity
13
four factors influencing melting point
-molecular symmetry
-molecular polarity
h-bondng
-molecular weight
14
mp of pentane
130 degree celsius
15
mp of 2,2-dimethylpropane
-17 degree celsius
16
h- bonds of benzoic acid
2
17
h-bonds of benzoic alcohol
1
18
the ability of molecules to pack together tightly influences what?
intermolecular interactions and melting point
19
tighter packing increases what?
melting point
20
have sharp melting point whereas mixtures melt with a broad temperature range
pure crystalline solids
21
even chains pack tighter than odd
true
22
molecules with this shape have unusually high melting points
spherical shapes
23
what device do we use to measure melting point?
electrothermal melt-point tester
24
what properties are melting and boiling points?
physical
25
if boiling does occur under these conditions, what will occur?
explosive violence
26
these can be used to identify the unknown drugs
melting and boiling point
27
the difference in boiling point informs the difference in
molecular structure
28
an antiseptic that has boilin gpoint higher than ether that was used as general anesthetic
phenol
29
measure of how much the speed of light is reeduced inside the medium
index of refraction
30
often used to identify a particular substance, confirm its purity, or measure its concentration
refractive index
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