Chapter 2 chemical properties

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1
carbohydrates
store energy reserves, structural framework of the cell, impart sugars
2
monosaccharides and dissacharides
two main type of sugars
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Monosaccharides
C6H1206
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Glucose
-also known as dextrose
- mildly sweet flavor
-most abundant simple carbohydrate
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Fructose
-aka fruit sugar
-sweetest of all sugar
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Sucrose
-table sugar
- glucose-fructose
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Lactose
-glucose-galactose
- milk sugar
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Maltose
-malt sugar
-breakdown product of starches
-glucose glucose
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Complex carbohydrates
-chains of more tha 2 sugar molecules
- (types) short and long
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Oligosaccharides
-short carb chain
-3-10 sugar molecules
- beans, peas and lentils also a dietary fiber (raffinose and stachyose)
- human milk (200 diff types)
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Polysaccharides
-long carb chain
- may be digestible (starch) or indigestible (fiber)
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Starch
-stored energy for growth and reproduction
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Amylose (starch)
-made up of long, unbranched chains of glucose molecules
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Amylopectin
made up of branched chains of glucose molecules
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resistant starch
Starch that is not digested
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glycogen
-Composed of long, highly branched chains of glucose molecules.
- animal starch
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Total Fiber
the sum of dietary fiber and functional fiber
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Dietary fiber
consists of indigestible carbohydrates (such as cellulose, or soluble and insoluble fiber) and lignins that are intact and intrinsic in plants.
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Functional fiber
- isolated, indigestible carbohydrates
-plant pectins, gums and resistant starches, chitin and chitosan,
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Cellulose
- long, straight chains of glucose molecules
- makes the walls of cells strong and rigid
- forms the woody fibers that support tall trees and the brittle shafts of hay and straw and the stringy threads in celery.
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Lignins
-indigestible substances that make up the woody parts of vegetables
- found in carrots, broccoli, and seeds of fruits
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Pectins
-gel-forming polysaccharides found in all plants, but especially fruits;
-soluble fiber
-apples have a lot of this
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Gums and mucilages
- thick, gel-forming fibers that help hold plant cells together like pectins;
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Chitin and chitosan
- polysaccharides found in the exoskeletons of crabs and lobsters, and in the cell walls of most fungi.
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Organic Acids
- exhibit acidic properties; exist as free acids, anions or combined with salts
- acidulants, flavorants, or preservatives,
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Citric Acid (fruits)
-tomato, calamondin,
-other citrus fruits; strawberry
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Malic acid (fruits)
banana, mango, eggplant, melon, carrot, grape
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Tartatic acid (fruits)
tamarind, grapes
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Oxalic acid (Fruits)
carambola, amaranth
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Ascorbic acid
all fruits and vegetables
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Amino acids and proteins
building blocks of life
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proteins
-regulate metabolism
- act as structural molecule
- represent a storage form of C and N
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classification of proteins and amino acids based on function
- essential
- non-essential
- conditional
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classification of proteins and amino acids based on composition
-simple: amino acids only (albumin, globulin, glutelin, prolamin)
-conjugate: combined with non-protein components (lipoprotein, glycoprotein, metalloprotein)
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classification of proteins and amino acids based on solubility
- albumin: soluble in water
- globulin: soluble in dilute salt solution
- glutelin: soluble in dilute acidase
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Lipids
group of compounds insoluble in water but dissolves in organic solvents
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Simple lipids (homolipids)
-esters of fatty acids with various alcohols
- fats and oils, waxes
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Compound lipids (heterolipids)
-have additional groups/elements besides fatty acids and alcohol
-phospholipids, glycolipids
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Derived lipids
-products of hydrolysis of simple and compound lipids
- steroids, terpenes, carotenoids
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Volatile compounds
-diverse array of chemical compounds (esters, aldehydes, ketones, alcohols, acids, acetals)
- present in small amounts
- provide a flavor fingerprint
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Plant pigments
-trap light energy
-prevent photo oxidation
- facilitate pollination
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Volatile matter
- CHO in a biomass
-when heated converted to vapor
-High amount implies easier ignition but much smoke
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Ash
- non-combustible component of a biomass
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Fixed carbom
percentage of carbon available for char combustion
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