1halogenation reagents
X2, FeX3
2nitration reagents of benzeneRCPO-Cl,
HNO3, H2SO4
3sulfonation reagents
H2SO4, SO3
4Friedel krafts alkylation reagents
R-Cl, AlCl3
5Friedel krafts acylation reagents
RCO-Cl, AlCl3
6how to tell if a carbon is sp2 hybridized
7what does a wolff-kishner reduction do and with what reagents
1) reduces aldehydes and ketones by removing the double bonded O. 2) KOH, N2H4
8the benzylic position can be:
oxidized, halogeenized
9peroxide reagent name what is NBS and what does it do
ROOR
10what does peroxide do
forces the reaction to the benzylic position
11attachment these in order of reactivity from least to most reactive:: 1) benzene 2) methylbenzene 3) niitrobenzene, 4)phenylamine (has NH2 group), 5)
12what is NBS and what does it do?
provides small amounts of Br radicals
13what does NBS + ROOR do with benzene
force the reaction at the benzylic position and adds a Br to that
14what does PCC do
oxidizes alcohols to form carbonyls
15wheat three things does nucleophilic aromatic substitution require
1)the ring had an electronic withdrawing group 2) a leaving group is present 3)the leaving group is ortho or para to the EWG
16NaO -et is
a nucleophile
17KMnO4 as a reagent
an oxidizing agent on crack
18KMnO4 needs ______ to react
an H bonded to the benzzykic C
19E1 is _____ step, E2 is _____ step
2. 1
20high temps tend to favor____ elimination
E1
21strong base tend to prefer _____ elimination
E2
22aldehyde structure
one R one H
23ketone structure
2 R groups
24how is an aldehyde formed
primary alcohol oxidation
25how is a ketone formed
secondary alcohol oxidation