1a property that does not affcet the chemical identity of a compound and can be observed and measured without changing a compounds composition of matter
physical property
2the physical properties of molecules are in part dependent of the types of
intermolecular forces
3are dependent on the mass of the molecule
boiling points
4the ability to dissolve into a solvent, is dependent on the IMF
solubility
5the strength of the interaction between molecules is also dependent on the
overall shapw of the molecule
6complex interaction that includes a dipole dipole, as well as orbital interactions and the transfer of electron density between molecules
hydrogen bonding
7these are the strongest of the IMF and ranges from
hydrogen bonding, 5-25 kJ/mol
8occur primarily between ON, NH and FH
hydrogen bonding
9the more EN the atom, the stronger the interaction
true
10forces arise from thr attraction of oppositely charged atoms in molecules
dipole dipole
11these are generally weaker than hydrogen bonding an ranges from
dipole dipole, 5-10 kJ/mol
12forces arise from the movement of electrons within a molecule which can produce an uneven distribution of the electrons resulting in a temporary dipole moment in the molecule
london dispersion
13these forces are very brief and weak, ranges from
london dispersion, 2-5 kJ/mol
14processes in which non covalent interactions between identical molecules in a pure sample are disrupted
boiling and melting point
15lower the compounds boiling point because it reduces the area of contact
branching
16occurs when one substance is converted into other substances, accompanied by breaking of some bnds and by making os some others
chemical reactions
17defined as the detailed knowledge of the steps involve in a process in which the reactant molecules change into products
reaction mechanism
18the breaking of a covalent bond is also known as
bond fission
19the fission of a covalen bond with equal sharing of bonding electros
homolytic fission
20neutral but reactive species having an unpaired electron and these can also initiate a chemical reaction
free radicals
21the fission of a covalent bond involving unequal sharing of bonding electrons
heterolytic fission
22heterolytic fission results in the formation of
ions
23the ion which has a positive charge on the carbon atom is known as the
carbonium ion or carbocation
24an ion with a negative charge on the carbon atom is known as
carbanion
25an electron deficient species and it may be positively charged or neutral
electrophiles
26negatively charged or electron rich neutral species
nucleophiles
27involves the displacement of one atom or group in a molecule by another atom or group
substitution
28these compounds can undergo nucleophilic substitutio n reactons
aliphatic compounds
29proceeds with a fundamental change in the hydrocarbon skeleton of the molecule, during this reaction, an atom or group migrates from one position to another
molecular rearrangements