3.3.6 ORGANIC ANALYSIS

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1
Alkene test?
Add bromine water to it.
If alkene itll turn brown to colourless
2
Alcohol test
Add small piece of metallic sodium
If alcohol lots of fizzing occurs
3
Carboxylic acid test
Add solid sodium hydrogen carbonate and bubble it through lime water
If carboxylic acid lime water turns cloudy
4
Aldehyde test?
Warm it up with Fehling's solution
If aldehyde itll turn blue to brick red colour
5
Halogenoalkane test
add NaOH and warm
acidify with nitric acid then add silver nitrate
If halo alkane:
Cl- = white
Br- = cream
I- = yellow
6
whats high resolution spectroscopy
Spectrometers that can measure up to 3 or 4 decimal points.
Allows us to work out molecular formulas of parent ions
7
How IR spectroscopy works
Bonds in molecules absorb specific frequencies and device detects transmittance of it
Low transmittance at a specific frequency means that molecule has that bond
8
How to tell difference between O-H in alcohols and acids
Alcohols - smooth curve and looks like a whale head
Acids - jagged and looks like a mountain range
9
What is the fingerprint region in IR
Below 1500 and patterns are unique for every molecule
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