Chem I Test 2

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1
Jules (units)
J or kgm2/s2
2
wavelength (units)
m (nm)
3
frequency (units)
s-1
4
energy (symbol)
E
5
frequency (symbol)
v (nu)
6
wavelength
lamda
7
photoelectric effect
electrons leave atom or rings when light hits them
8
line spectra
show wavelengths of light emitted when electrons jump rings
9
Bohr's model
shows orbitals, orbits, and levels
10
deBroglie wavelength
Idea that if light acts as both a particle and a wave, it can behave as both a particle and a wave
11
what does deBroglie's wavelength show?
wavelength associated with momentum and mass
12
Heisenberg's uncertainty principle
idea that one can't see an electron as a wave and a partcile at the same time because they are complimentary principles and cancel each other out
13
Probability distribution
Idea that we know where the electron is likely to be, but not really
14
quantum numbers (definition)
short-hand numbers to describe e- configuration
15
Principle quantum number
n, shell number, determined by row #
16
Angular Momentum quantum number
l, subshell, describes shape of orbital; determined by block
17
l of s orbital
0
18
l of p orbital
1
19
l of d orbital
2
20
l of f orbital
3
21
Magnetic quantum number
ml, orientation of orbital in space; determined by -l through +l
22
Magnetic spin quantum number
1/2 positive (spin up) vs -1/2 negative (spin down)
23
Pauli's exclusion principle
No two elecctrons in an atom have the same set of 4 quantum numbers
24
Pattern in # of orbitals
n^2 = # of orbitals
25
Pattern in # of electrons
# of orbitals * 2
26
Hund's rule
electrons will fill empty spin up and spin down orbitals before they'll fill full ones
27
valence electrons
outermost electrons, used in bonding; use ns + nblock
28
core electrons
electrons deep inside atom
29
Exceptions to normal electron configurations
Cr, Mo, Cu, Ag
30
Cr Configuration
[Ar] 4s13d5
31
Mo configuration
[Kr] 5s14d5
32
Cu configuration
[Ar] 4s14d10
33
Ag configuration
[Kr] 5s14d10
34
column 1 of periodic table
alkali metals
35
column 2 of periodic table
alkalines earth metals
36
column 6 of periodic table
Chalcogens
37
column 7 of periodic table
Halogens
38
column 8 of periodic table
noble gases
39
transition metals
columns 3-12
40
lanthanides
#57-71
41
Actinodes
#89-102
42
ionic bonds
metal and nonmetal
43
covalent
nonmetal and nonmetal
44
electronegativity
tendency of an atom to attract electrons
45
pure covalent difference in electronegativity
0.4 or less
46
polar covalent difference in electronegativity
0.4-2.0
47
ionic difference in electronegativity
2.00 or more
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