Chem I Test 2

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1
Jules (units)
J or kgm2/s2
2
wavelength (units)
m (nm)
3
frequency (units)
s-1
4
energy (symbol)
E
5
frequency (symbol)
v (nu)
6
wavelength
lamda
7
photoelectric effect
electrons leave atom or rings when light hits them
8
line spectra
show wavelengths of light emitted when electrons jump rings
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Bohr's model
shows orbitals, orbits, and levels
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deBroglie wavelength
Idea that if light acts as both a particle and a wave, it can behave as both a particle and a wave
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what does deBroglie's wavelength show?
wavelength associated with momentum and mass
12
Heisenberg's uncertainty principle
idea that one can't see an electron as a wave and a partcile at the same time because they are complimentary principles and cancel each other out
13
Probability distribution
Idea that we know where the electron is likely to be, but not really
14
quantum numbers (definition)
short-hand numbers to describe e- configuration
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Principle quantum number
n, shell number, determined by row #
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Angular Momentum quantum number
l, subshell, describes shape of orbital; determined by block
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l of s orbital
0
18
l of p orbital
1
19
l of d orbital
2
20
l of f orbital
3
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Magnetic quantum number
ml, orientation of orbital in space; determined by -l through +l
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Magnetic spin quantum number
1/2 positive (spin up) vs -1/2 negative (spin down)
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Pauli's exclusion principle
No two elecctrons in an atom have the same set of 4 quantum numbers
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Pattern in # of orbitals
n^2 = # of orbitals
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Pattern in # of electrons
# of orbitals * 2
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Hund's rule
electrons will fill empty spin up and spin down orbitals before they'll fill full ones
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valence electrons
outermost electrons, used in bonding; use ns + nblock
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core electrons
electrons deep inside atom
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Exceptions to normal electron configurations
Cr, Mo, Cu, Ag
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Cr Configuration
[Ar] 4s13d5
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Mo configuration
[Kr] 5s14d5
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Cu configuration
[Ar] 4s14d10
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Ag configuration
[Kr] 5s14d10
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column 1 of periodic table
alkali metals
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column 2 of periodic table
alkalines earth metals
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column 6 of periodic table
Chalcogens
37
column 7 of periodic table
Halogens
38
column 8 of periodic table
noble gases
39
transition metals
columns 3-12
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lanthanides
#57-71
41
Actinodes
#89-102
42
ionic bonds
metal and nonmetal
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covalent
nonmetal and nonmetal
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electronegativity
tendency of an atom to attract electrons
45
pure covalent difference in electronegativity
0.4 or less
46
polar covalent difference in electronegativity
0.4-2.0
47
ionic difference in electronegativity
2.00 or more
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