1the ones we use as raw materials to synthesize other organic compounds
Alcohols
2may give aldehydes, ketones or carboxylic acids
Oxidation
3can be used in subsequent grignards reactions
Ketones and Aldehydes
4the one we can use for esterification
Carboxylic acids
5would yield an aldehyde if oxidized
Primary alcohol
6further oxidation of the aldehyde would yield
Carboxylic acid
7would yield a ketone if oxidized
Secondary alcohol
8no further oxidation is observed, cannot be oxidized at all without breaking carbon carbon compounds
Tertiary alcohol
9oxidation of alcohol need this as an effective oxidizng agent
chromic acid and sulfuric acid
10oxidizes alcohol without breaking carbon carbon compounds
chromic acid
11will not react with chromic acids under mild conditions
Tertiary alcohols
12PCC stand for
pyridinium chlorochromate
13a special reagent wich is a milder oxidant than chromic acid which is a strong one
PCC
14PCC only oxides primary alcohols to form
aldehydes
15PCC is made up of
chromium trioxide with pyridine and hydrogen chloride
16Alcohols when dehydrated would yield
alkenes
17removal of hydroxyl group and water
Dehydration
18most commonly carried out by warming alcohol with a dehydrating agent which is sulfuric acid
Dehydration reactions
19alcohols can also be dehydrated to become
ethers
20can undergo intermolecular dehydration to form ethers
simple alcohols
21ethano is dehydrated to yield
diethyl ether
22forms alkyl halides
substitution
23often synthesized to form alcohols so it would be by having a halogen substitute the hydroxyl group
Substitution
24alkyl chlorides
thionyl chloride
25alkyl bromides
phosphorus tribromide
26alkyl iodides
phosphorus triodide
27this usually yields an ester
Esterification
28carboxylic acid plus alcohol
carboxylic ester
29esterification is also under the reaction of
fischers esterification
30still alcohol but here you have the hydroxyl group attached to an aromatic ring
Phenols
31simplest phenol
monohydroxybenzene
32monohydroxybenene is also known as
benzenol or carbolic acid
33are only slightly soluble in water but miscible with other solvents
monohydroxy compounds
34either corrosive liquids or low mwlting solids
simple monohydric phenols
35solid phenols
dihydric and trihydric
36who discovered phenols?
Joseph Lister
37have supplanted phenol itself in cough drops and other antiseptic applications
n-hexylresorcinol
38much lower toxicity and is common antioxidant in foods
butylated hydroxytoluene
39one of the standard amino acid found in most proteins
tyrosine
40also known as adrenaline, stimulant hormone produced by the adrenal medulla
epinephrine
41neurotransmitter in the brain
serotoninn
42irritant secreted by poison ivy to prevent animal from eating its leaves
urushiol
43principal flavoring in vanilla, isolated from vanilla beans
vanillin
44has a characteristic of minty taste and odor, is isolated from wintergreen
methyl salicylate
45extracted from thyme and fungicidal
thymol
46extracted from clove oil, antisetic in mouthwashes and dental analgesic
eugenol