1Define atom
the smallest component of an element having the chemical properties of that element
2protons and neutrons (1 word)
nucleons
3relative mass of subatomic particles (1)
Proton: 1
Neutron: 1
Electron: 1/1836
4a
. X
z
A= mass number
X= element symbol
Z= atomic number
5proton number/atomic number
number of protons in the nucleus of each atom of an element
6nucleon number/mass number
number of neutrons and protons in the nucleus of each atom of an element
7isotope
an atom of an element with the same number of protons but different number of neutrons
8how are isotopes similar and different from each other ? (2,2)
they have the same electronic configuration and chemical properties, but different relative isotopic masses and physical properties
9isotopes may be stable or unstable
10anion
a negatively charged atom/molecule with more electrons than protons
11cation
a positively charged ion that has fewer electrons than protons
12in an electric field: how would a proton, neutron and electron behave?
proton: deflected to the negative plate
neutron: goes straight through the field
electron: deflected to the positive plate
note that electrons will be deflected at a greater angle than protons because they are lighter
13angle of deflection formula (of a charged particle)
theta = (q/m) k
k is a constant,
q = charge
m = mass
theta = angle of deflection
14relative atomic mass (Ar)
(average mass of one atom of an element) / (1/12 x mass of one carbon-12 atom)
or:
the ratio of the average mass of one atom of an element to the mass of 1/12 of a carbon-12 atom
15relative isotopic mass
(mass of one atom of an isotope of an element) / (1/12 x the mass of one atom of carbon-12)
or
the ratio of one atom of an isotope of an element to the mass of 1/12 of one atom of a carbon-12 atom
16isotopic abundance / relative abundance
the abundance of each isotope in a mixture
17what is the principal quantum number and what does it mean
it is a set of numbers used to describe the main energy level of an electron
indicates:
relative size of the orbital
relative distance of the electron from the nucleus
bigger n = higher energy level, further distance between electron and nucleus
18maximum number of electrons in a quantum shell
2n^2
19number of subshells in a principal quantum shell is the same as the shell's principal quantum number
20atomic orbital
region of space where there is >90% probability of finding an electron
21each subshell has one or more orbitals at the same energy level but different orientations in space
22electrons in an orbital (2)
max 2, in opposite spins
23shape of s and p orbitals
s: spherical
p: dumbbell
24go draw and label all d orbitals
25aufbau (building up) principle
electrons in their ground states occupy orbitals in order of energy levels. the orbital with the lowest energy will be filled first
26hund's rule of multiplicity
when filling subshells with more than one orbital, each orbital must be singly occupied before electrons are paired
27pauli exclusion principle
an orbital can hold a maximum of 2 electrons and they must have opposite spins
28valence electron configuration for s-block and p-block
period is the quantum number
group:
1. ns1
2. ns2
13. ns2np1
14. ns2np2
15. ns2np3
16. ns2np4
17. ns2np5
18. ns2np6
29transition metal
a d-block element that forms one or more stable ions with a partially filled d-subshell
30d-block elements that are not transition metals and why:
Zinc and scandium
Zn only forms Zn2+ (3d10)
Sc only forms Sc3+ (3d0)
31ground state
all electrons are at their lowest possible energy levels
32ionic and atomic radii factors (2)
1. number of quantum shells
2. effective nuclear charge
33effective nuclear charge
the net nuclear charge experienced by an outer electron
34nuclear charge factor
number of protons
35shielding effect
presence of inner shell electrons reduces electrostatic attraction between the outermost electrons and the nucleus
36atomic radius trend down group
increases:
as number of quantum shells increase, electrons are further away from the nucleus and radius increases
both nuclear charge and shielding effect increases down the group and hence effective nuclear charge differs little down the group
37atomic radius trend across period
decreases across period
nuclear charge increases due to increase in number of protons in nucleus
shielding effect remains constant
effective nuclear charge increases
stronger electrostatic forces of attraction, atomic radius decreases
from Na to Cl -> decrease
from Cl to Ar -> massive increase
because for other elements, the atomic radii refers to the covalent radii, but for noble gases it's the van the waal's radius