1. atomic structure

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1
Define atom
the smallest component of an element having the chemical properties of that element
2
protons and neutrons (1 word)
nucleons
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relative mass of subatomic particles (1)
Proton: 1
Neutron: 1
Electron: 1/1836
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a
. X
z
A= mass number
X= element symbol
Z= atomic number
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proton number/atomic number
number of protons in the nucleus of each atom of an element
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nucleon number/mass number
number of neutrons and protons in the nucleus of each atom of an element
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isotope
an atom of an element with the same number of protons but different number of neutrons
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how are isotopes similar and different from each other ? (2,2)
they have the same electronic configuration and chemical properties, but different relative isotopic masses and physical properties
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isotopes may be stable or unstable
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anion
a negatively charged atom/molecule with more electrons than protons
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cation
a positively charged ion that has fewer electrons than protons
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in an electric field: how would a proton, neutron and electron behave?
proton: deflected to the negative plate
neutron: goes straight through the field
electron: deflected to the positive plate

note that electrons will be deflected at a greater angle than protons because they are lighter
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angle of deflection formula (of a charged particle)
theta = (q/m) k
k is a constant,
q = charge
m = mass
theta = angle of deflection
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relative atomic mass (Ar)
(average mass of one atom of an element) / (1/12 x mass of one carbon-12 atom)
or:
the ratio of the average mass of one atom of an element to the mass of 1/12 of a carbon-12 atom
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relative isotopic mass
(mass of one atom of an isotope of an element) / (1/12 x the mass of one atom of carbon-12)
or
the ratio of one atom of an isotope of an element to the mass of 1/12 of one atom of a carbon-12 atom
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isotopic abundance / relative abundance
the abundance of each isotope in a mixture
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what is the principal quantum number and what does it mean
it is a set of numbers used to describe the main energy level of an electron
indicates:
relative size of the orbital
relative distance of the electron from the nucleus

bigger n = higher energy level, further distance between electron and nucleus
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maximum number of electrons in a quantum shell
2n^2
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number of subshells in a principal quantum shell is the same as the shell's principal quantum number
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atomic orbital
region of space where there is >90% probability of finding an electron
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each subshell has one or more orbitals at the same energy level but different orientations in space
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electrons in an orbital (2)
max 2, in opposite spins
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shape of s and p orbitals
s: spherical
p: dumbbell
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go draw and label all d orbitals
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aufbau (building up) principle
electrons in their ground states occupy orbitals in order of energy levels. the orbital with the lowest energy will be filled first
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hund's rule of multiplicity
when filling subshells with more than one orbital, each orbital must be singly occupied before electrons are paired
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pauli exclusion principle
an orbital can hold a maximum of 2 electrons and they must have opposite spins
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valence electron configuration for s-block and p-block
period is the quantum number
group:
1. ns1
2. ns2
13. ns2np1
14. ns2np2
15. ns2np3
16. ns2np4
17. ns2np5
18. ns2np6
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transition metal
a d-block element that forms one or more stable ions with a partially filled d-subshell
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d-block elements that are not transition metals and why:
Zinc and scandium
Zn only forms Zn2+ (3d10)
Sc only forms Sc3+ (3d0)
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ground state
all electrons are at their lowest possible energy levels
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ionic and atomic radii factors (2)
1. number of quantum shells
2. effective nuclear charge
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effective nuclear charge
the net nuclear charge experienced by an outer electron
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nuclear charge factor
number of protons
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shielding effect
presence of inner shell electrons reduces electrostatic attraction between the outermost electrons and the nucleus
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atomic radius trend down group
increases:
as number of quantum shells increase, electrons are further away from the nucleus and radius increases

both nuclear charge and shielding effect increases down the group and hence effective nuclear charge differs little down the group
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atomic radius trend across period
decreases across period

nuclear charge increases due to increase in number of protons in nucleus

shielding effect remains constant

effective nuclear charge increases

stronger electrostatic forces of attraction, atomic radius decreases

from Na to Cl -> decrease
from Cl to Ar -> massive increase
because for other elements, the atomic radii refers to the covalent radii, but for noble gases it's the van the waal's radius
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