Organic Chemistry - Reagent Conditions (Aldehydes and Ketones)
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1
What reagent reduces aldehydes, ketones, carboxylic acid, and esters to a primary alcohol
1) LiAlH, Et2O 2) H2O
2
What reagent reduces ketones and aldehydes to a primary alcohol
1)NaBH4 2) H2O
3
What reagent reduces an ester to an aldehyde
1)DIBAL-H, hexane, -78 2) H2O
4
What reagent reduces a nitrile to an aldehyde
1) DIBAL, Hexane 2) H2O
5
What reagent oxidizes primary alcohols to aldehydes
PCC, CH2Cl2
or
DMP, CH2Cl2
or
1) DMSO, (COCl)2
2) Et3N
or
DMP, CH2Cl2
or
1) DMSO, (COCl)2
2) Et3N
6
What reagent ozonolysis of alkenes to aldehydes
1) O3
2) DMS
2) DMS
7
What reagent hydroboration-oxidation of terminal alkynes to aldehydes
1) R2B-H
2) H2O2, NaOH
2) H2O2, NaOH
8
What reagent oxidizes secondary alcohols to ketones
Na2Cr2O7
H2SO4, H2O
H2SO4, H2O
9
What reagent ozonolysis of alkenes to ketones
1) O3
2) DMS
2) DMS
10
What reagent acid-catalyzed hydration of terminal alkynes to ketones
H2SO4, H2O
HgSO4
HgSO4
11
What reagent friedel-crafts acylation to ketones
Acyl chloride
AlCl3
AlCl3
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