1electromagnetic radiation
consists of oscillating electric ad magnetic fields that are perpendicular to each other
2wavelength (m)
-distance between identical points on successive waves
3frequency (Hz)
- number of waves that pass through a particular point in one second
-1 cycle/s
4amplitude
the vertical distance from the midline of a wave to the peak or trough
5 when allobjects Em radiation whose wavelegth and color depends on the temperature of the object
when heated allobjects Em radiation whose wavelegth and color depends on the temperature of the object
6quantum theory
energy is emitted from a heated body only in discrete little packets
7quantum
smallest amount of energy that can be emitted or absorbed in the form of EMR
8Photoelectric Effect
-phenomenon in which electron sare ejected from the surface of certain metals exposed to light
9electrons can only be ejected from the surface of the metal if the energy of the incident light is the threshold frequency
electrons can only be ejected from the surface of the metal if the energy of the incident light is greater than the threshold frequency
10Bohr Orbit (n)
defines the energy level and the position of the electron
11De Broglie Relation
wave-like properties of matter
12Heisenberg's Uncertainty principle
it is impossible to know both the momentum and the position of a particle with certainty
13Schrodinger Wave Equation
uses wave function to describe the energy of e-
14quantum numbers
the allowed energy states of atoms and molecules can be described by sets of number
15orbital
region of space where the electron is most likely be found
16Principal QN (n)
determines the energy of an interval
17Angular QN (l)
describes the shape of an orbital
18Magnetic QN (ml)
-describes the orientation of orbitals in space
-designates a specific orbital within a subshell
- also indicate the number of degenerate orbitals
19Degenerate orbitals
orbitals of the same energy
20Spin QN (ms)
accounts for two possible spinning motion of electrons in an orbital
21Ground state
lowest energy arrangement of the electrons around the atom
22Aufbau Principle (Building Up Principle)
electrons occupy the available orbitals in order of increasing energy.
23Hund's Rule of Multiplicity
all degenerate orbitals in given subshll are singly occupied by electrons before pairing begins
24Pauli's Exclusion principle
no two electron in an atom can have the same set of four quantum numbers
25Isoelectronic
-have the same number of electron
-same ground-state electron configuration
26effective nuclear charge (Zeff)
-the "positive charge"felt by an electron
-higher value, stronger attraction of the outermost electron to the nucleus
27Electron Affinity
theenergy change that occurs when an electron is added to a gaseous atom (or atom)
28Affinity for an Electron
- tendency of an atom to attract an additional electron
- measured by EA