LECTURE 1

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1
electromagnetic radiation
consists of oscillating electric ad magnetic fields that are perpendicular to each other
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wavelength (m)
-distance between identical points on successive waves
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frequency (Hz)
- number of waves that pass through a particular point in one second
-1 cycle/s
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amplitude
the vertical distance from the midline of a wave to the peak or trough
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when   allobjects Em radiation whose wavelegth and color depends on the temperature of the object
when heated allobjects Em radiation whose wavelegth and color depends on the temperature of the object
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quantum theory
energy is emitted from a heated body only in discrete little packets
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quantum
smallest amount of energy that can be emitted or absorbed in the form of EMR
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Photoelectric Effect
-phenomenon in which electron sare ejected from the surface of certain metals exposed to light
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electrons can only be ejected from the surface of the metal if the energy of the incident light is   the threshold frequency
electrons can only be ejected from the surface of the metal if the energy of the incident light is greater than the threshold frequency
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Bohr Orbit (n)
defines the energy level and the position of the electron
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De Broglie Relation
wave-like properties of matter
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Heisenberg's Uncertainty principle
it is impossible to know both the momentum and the position of a particle with certainty
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Schrodinger Wave Equation
uses wave function to describe the energy of e-
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quantum numbers
the allowed energy states of atoms and molecules can be described by sets of number
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orbital
region of space where the electron is most likely be found
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Principal QN (n)
determines the energy of an interval
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Angular QN (l)
describes the shape of an orbital
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Magnetic QN (ml)
-describes the orientation of orbitals in space
-designates a specific orbital within a subshell
- also indicate the number of degenerate orbitals
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Degenerate orbitals
orbitals of the same energy
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Spin QN (ms)
accounts for two possible spinning motion of electrons in an orbital
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Ground state
lowest energy arrangement of the electrons around the atom
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Aufbau Principle (Building Up Principle)
electrons occupy the available orbitals in order of increasing energy.
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Hund's Rule of Multiplicity
all degenerate orbitals in given subshll are singly occupied by electrons before pairing begins
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Pauli's Exclusion principle
no two electron in an atom can have the same set of four quantum numbers
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Isoelectronic
-have the same number of electron
-same ground-state electron configuration
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effective nuclear charge (Zeff)
-the "positive charge"felt by an electron
-higher value, stronger attraction of the outermost electron to the nucleus
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Electron Affinity
theenergy change that occurs when an electron is added to a gaseous atom (or atom)
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Affinity for an Electron
- tendency of an atom to attract an additional electron
- measured by EA
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