1Emphasizes the role of particle motion
kinetic molecular theory of liquids and solids
2In liquids, the molecules are in constant motion
particle motion
3liquids are characterized by moderate intermolecular forces
intermolecular forces
4liquids have a higher density compared to gases
density and compressibility
5In solids, the particles are closely packed in a regular
particle arrangement
6solids have strong intermolecular forces that hold the particles
strong intermolecular forces
7solids are nearly due to the close arrangement of particles
low compressibility
8It occurs between polar covalent molecules
Dipole dipole forces
9are forces between individual particle such as atoms ions and molecule
Intermolecular forces
10These weak forces of attraction in non polar substances
Van der Waals forces or dispersion forces
11the attraction between a highly electronegative atom and a hydrogen
hydrogen bond
12 meaning they occupy a specific amount of space
definite volume
13unlike solids that have a fixed and definite shape
indefinite shape
14liquids have a higher density compared to gases
Density
15liquids are generally considered to be ?
Incompressibility
16liquids exhibit limited ______ compared to gases
diffusion
17is a measure of a liquid resistance to flow
viscosity
18is the tendency of the surface of a liquid to resist external forces
surface tension
19liquids can rise or fall in narrow tubes due to ?
capillary action
20liquids have distinct _____ at specific temperatures
boiling and freezing points
21refers to the ordered arrangement of atoms ions or molecules
Crystal Structure
22is a powerful technique used to study the structure of crystalline materials
X-ray diffraction
23The diffraction of X rays by a crystal is based on ?
Bragg's Law
24the x-ray _______ is recorded on a detector and consist of a series of bright spots
diffraction pattern
25by analyzing the diffraction pattern scientist can determine the three dimensional arrangement of atoms
Crystal structure determination
26Typically x ray Diffraction experiments use a x-ray procured bynxbray tubes
x ray Sources
27Can be classified into various types based on their structure
Crystals
28Composed of ions held together by ionic bonds
Ionic crystals
29composed of atoms linked by covalent bonds forming a continuous network
covalent crystals
30composed of metal atoms held together by metallic bonds
Metallic crystals
31composed of molecules held together intermolecular
molecular crystals
32solids are a class of solid materials that lack the long range order
Amorphous solids
33Glass is a common example of an amorphous solid
Amorphous Silica
34many Polymers in their glassy state
amorphous Polymer
35Some metal alloys can be rapidly cooled to form amorphous structures
Amorphous Metals
36a measure of the strength of intermolecular forces in a liquid
Heat of vaporization and boiling point
37represented in a phase describes conditions
Liquid solid equilibrium
38that hold molecules together in liquids and solids also play a central role
Intermolecular Attraction
39the presence of non a volatile solute in a solvent lowers the ?
Vapor pressure lowering
40the ____ of a solution is higher than that of the pure solvent.
boiling point elevation
41the _______of a solution is lower than that of the pure solvent.
Freezing point depression
42the pressure required to stop the flow of solvent molecules through a semipermeable
osmotic Pressure
43represent the number of ions produced by a solute in a solution due to dissociation
Can't Hoff factor
44Electrolytes lower the ______ more than non electrolytes
Vapor pressure lowering
45Electrolytes cause a greater increase in the
Boiling point elevation
46electrolytes lead to more pronounced lowering of the ____
freezing point depression
47electrolytes contribute to ____
osmotic pressure
48areq types of mixture where one substance is dispersed I'm another in the form of small particles.
Colloids
49Is a fundamental concept in physics
Energy
50the internal energy of a substance due to the movement of it's atoms and molecules
Thermal Energy
51Energy stored in the chemical bonds of molecules
Chemical Energy
52energy carried by electromagnetic waves
Electromagnetic energy
53energy stored in the nucleus of an atom
nuclear energy
54the energy associated with the vibration of particles in a medium
Sound energy
55the potential energy an object has due to its position in a ?
Gravitational Energy
56Three system represented by water
Open system, closed system, isolated system
57Reactions release energy to the surroundings
Exothermic
58reaction absorb energy from the surroundings
Endothermic
59is the minimum energy required to initiate a chemical reaction
Activation energy
60Reaction must overcome this energy ____
energy barrier
61can lower the activitation energy, facilitating the reaction without being consumed
catalyst
62is a thermodynamic quantity that represents the total heat content of a system
Enthalpy
63is a branch of thermodynamics that involves measurement of heat transfer
Calorimetry
64Is a branch of physical science that deals with the principle governing energy
thermodynamics
65if two systems are each in thermal equilibrium with a Third system
Zeroth law
66energy cannot be created or destroyed
First law
67In any energy transformation or transfer the total entropy of a close system increased
Second Law
68as the temperature of a system approaches absolute zero
Third Law
69this is the physical property of a soluted depends on the number of solute particles
colligative property
70the addition of non volatile solute to a solvent makes the ______ of the solution lower that that of solvent alone
vapor pressure lowering
71the addition of a non volatile solute to a solvent makes the _____ of the solution higher than that of the solvent alone
Boiling point Elevation
72The addition of a non volatile solute to a solvent makes the ______ of the solution lower than that of the solvent alone
Freezing point depression
73the pressure required to stop the net flow of water across a membrane separating solution differing composition
Osmotic Pressure
74what are the osmotic pressure
Hypertonic, Hypotonic , Isotonic
75Solution with an osmotic pressure lower than that in cells
hypotonic
76solution with an osmotic pressure higher than that in cells.
Hypertonic solution
77Solution with an osmotic pressure equal to that of the cell
isotonic solution
78the first aspect pertains with energy changed that accompany physical and chemical processes that evolve heat and know as
thermochemistry
79is a chemical equation that includes the amount of energy
thermochemical equation
80allowed us to use standard heats of formation to indirectly calculate the heat if reaction
Hess's Law