Gen Chem 3R

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1
Emphasizes the role of particle motion
kinetic molecular theory of liquids and solids
2
In liquids, the molecules are in constant motion
particle motion
3
liquids are characterized by moderate intermolecular forces
intermolecular forces
4
liquids have a higher density compared to gases
density and compressibility
5
In solids, the particles are closely packed in a regular
particle arrangement
6
solids have strong intermolecular forces that hold the particles
strong intermolecular forces
7
solids are nearly due to the close arrangement of particles
low compressibility
8
It occurs between polar covalent molecules
Dipole dipole forces
9
are forces between individual particle such as atoms ions and molecule
Intermolecular forces
10
These weak forces of attraction in non polar substances
Van der Waals forces or dispersion forces
11
the attraction between a highly electronegative atom and a hydrogen
hydrogen bond
12
meaning they occupy a specific amount of space
definite volume
13
unlike solids that have a fixed and definite shape
indefinite shape
14
liquids have a higher density compared to gases
Density
15
liquids are generally considered to be ?
Incompressibility
16
liquids exhibit limited ______ compared to gases
diffusion
17
is a measure of a liquid resistance to flow
viscosity
18
is the tendency of the surface of a liquid to resist external forces
surface tension
19
liquids can rise or fall in narrow tubes due to ?
capillary action
20
liquids have distinct _____ at specific temperatures
boiling and freezing points
21
refers to the ordered arrangement of atoms ions or molecules
Crystal Structure
22
is a powerful technique used to study the structure of crystalline materials
X-ray diffraction
23
The diffraction of X rays by a crystal is based on ?
Bragg's Law
24
the x-ray _______ is recorded on a detector and consist of a series of bright spots
diffraction pattern
25
by analyzing the diffraction pattern scientist can determine the three dimensional arrangement of atoms
Crystal structure determination
26
Typically x ray Diffraction experiments use a x-ray procured bynxbray tubes
x ray Sources
27
Can be classified into various types based on their structure
Crystals
28
Composed of ions held together by ionic bonds
Ionic crystals
29
composed of atoms linked by covalent bonds forming a continuous network
covalent crystals
30
composed of metal atoms held together by metallic bonds
Metallic crystals
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composed of molecules held together intermolecular
molecular crystals
32
solids are a class of solid materials that lack the long range order
Amorphous solids
33
Glass is a common example of an amorphous solid
Amorphous Silica
34
many Polymers in their glassy state
amorphous Polymer
35
Some metal alloys can be rapidly cooled to form amorphous structures
Amorphous Metals
36
a measure of the strength of intermolecular forces in a liquid
Heat of vaporization and boiling point
37
represented in a phase describes conditions
Liquid solid equilibrium
38
that hold molecules together in liquids and solids also play a central role
Intermolecular Attraction
39
the presence of non a volatile solute in a solvent lowers the ?
Vapor pressure lowering
40
the ____ of a solution is higher than that of the pure solvent.
boiling point elevation
41
the _______of a solution is lower than that of the pure solvent.
Freezing point depression
42
the pressure required to stop the flow of solvent molecules through a semipermeable
osmotic Pressure
43
represent the number of ions produced by a solute in a solution due to dissociation
Can't Hoff factor
44
Electrolytes lower the ______ more than non electrolytes
Vapor pressure lowering
45
Electrolytes cause a greater increase in the
Boiling point elevation
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electrolytes lead to more pronounced lowering of the ____
freezing point depression
47
electrolytes contribute to ____
osmotic pressure
48
areq types of mixture where one substance is dispersed I'm another in the form of small particles.
Colloids
49
Is a fundamental concept in physics
Energy
50
the internal energy of a substance due to the movement of it's atoms and molecules
Thermal Energy
51
Energy stored in the chemical bonds of molecules
Chemical Energy
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energy carried by electromagnetic waves
Electromagnetic energy
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energy stored in the nucleus of an atom
nuclear energy
54
the energy associated with the vibration of particles in a medium
Sound energy
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the potential energy an object has due to its position in a ?
Gravitational Energy
56
Three system represented by water
Open system, closed system, isolated system
57
Reactions release energy to the surroundings
Exothermic
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reaction absorb energy from the surroundings
Endothermic
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is the minimum energy required to initiate a chemical reaction
Activation energy
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Reaction must overcome this energy ____
energy barrier
61
can lower the activitation energy, facilitating the reaction without being consumed
catalyst
62
is a thermodynamic quantity that represents the total heat content of a system
Enthalpy
63
is a branch of thermodynamics that involves measurement of heat transfer
Calorimetry
64
Is a branch of physical science that deals with the principle governing energy
thermodynamics
65
if two systems are each in thermal equilibrium with a Third system
Zeroth law
66
energy cannot be created or destroyed
First law
67
In any energy transformation or transfer the total entropy of a close system increased
Second Law
68
as the temperature of a system approaches absolute zero
Third Law
69
this is the physical property of a soluted depends on the number of solute particles
colligative property
70
the addition of non volatile solute to a solvent makes the ______ of the solution lower that that of solvent alone
vapor pressure lowering
71
the addition of a non volatile solute to a solvent makes the _____ of the solution higher than that of the solvent alone
Boiling point Elevation
72
The addition of a non volatile solute to a solvent makes the ______ of the solution lower than that of the solvent alone
Freezing point depression
73
the pressure required to stop the net flow of water across a membrane separating solution differing composition
Osmotic Pressure
74
what are the osmotic pressure
Hypertonic, Hypotonic , Isotonic
75
Solution with an osmotic pressure lower than that in cells
hypotonic
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solution with an osmotic pressure higher than that in cells.
Hypertonic solution
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Solution with an osmotic pressure equal to that of the cell
isotonic solution
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the first aspect pertains with energy changed that accompany physical and chemical processes that evolve heat and know as
thermochemistry
79
is a chemical equation that includes the amount of energy
thermochemical equation
80
allowed us to use standard heats of formation to indirectly calculate the heat if reaction
Hess's Law
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