Unit 4 pathways

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1
What is the type of reaction and conditions neccesary for the formation of a Alcohol from a alkene?
hydration, Steam, phosphoric acid catalyst, 60-70atm, 300°c
2
What is the type of reaction and conditions neccesary for the formation of a Haloalkane from a Alkene?
electrophilic addition, Br₂
3
What is the type of reaction and conditions neccesary for the formation of a Alkane from a Alkene?
catalytic hydrogenation, Ni catalyst, H₂
4
What is the type of reaction and conditions neccesary for the formation of a Haloalkane from a Alkane?
free radical substitution, UV light
5
What is the type of reaction and conditions neccesary for the formation of a Alkene from a Haloalkane?
elimination, NaOH/ethanol
6
What is the type of reaction and conditions neccesary for the formation of a Amine from a Haloalkane?
nucelophilic substitution, Ethanolic NH3l₃ in a sealed tube
7
What is the type of reaction and conditions neccesary for the formation of a Alcohol from a Haloalkane?
nucleophilic substitution, Aqeous NaOH, reflux
8
What is the type of reaction and conditions neccesary for the formation of a Nitrile from a Haloalkane?
nucelophilic substitution, KCN and dilute H₂SO₄
9
What is the type of reaction and conditions neccesary for the formation of a Aldehyde from a Alcohol?
oxidation, Primary alcohol and acidified K₂Cr₂O₇ heat and reflux
10
What is the type of reaction and conditions neccesary for the formation of a Ketone from a Alcohol?
oxidation, Secondary alcohol and acidified K₂Cr₂O₇ heat and reflux
11
What is the type of reaction and conditions neccesary for the formation of a Carboxylic acid from a Alcohol?
oxidation, Primary alcohol and acidified K₂Cr₂O₇ heat and reflux
12
What is the type of reaction and conditions neccesary for the formation of a Alkene from a Alcohol?
elimination dehydration, Conc H₂SO₄ or Al₂O₃ and heat
13
What is the type of reaction and conditions neccesary for the formation of a Ester using a carboxylic from a Alcohol?
esterification, Concentrated H₂SO₄, disitll product off
14
What is the type of reaction and conditions neccesary for the formation of a Esterl using an acid chloride from a Alcohol?
esterification, Ethanoyl chloride
15
What is the type of reaction and conditions neccesary for the formation of a Chloroalkane from a Alcohol?
chlorination. , Gaseous HCl and a ZnCl₂ catalyst
16
What is the type of reaction and conditions neccesary for the formation of a Chloroalkane from a Alcohol?
chlorination. , PCl₅
17
What is the type of reaction and conditions neccesary for the formation of a Chloroalkane from a Alcohol?
chlorination. , SOCl₂
18
What is the type of reaction and conditions neccesary for the formation of a Bromoalkane from a Alcohol?
bromination. , KBr and H₂SO₄
19
What is the type of reaction and conditions neccesary for the formation of a Iodoalkane from a Alcohol?
iodonation, Damp warm red phsophorus
20
What is the type of reaction and conditions neccesary for the formation of a 1* alcohol from a Aldehyde?
reduction, NaBH₄
21
What is the type of reaction and conditions neccesary for the formation of a Hydroxynitrile from a Aldehyde?
nucleophilic addition , KCN and dilute H₂SO₄
22
What is the type of reaction and conditions neccesary for the formation of a 2* alcohol from a Ketone?
reduction, NaBH₄
23
What is the type of reaction and conditions neccesary for the formation of a Hydroxynitrile from a Ketone?
nucleophilic addition , KCN and dilute H₂SO₄
24
What is the type of reaction and conditions neccesary for the formation of a Carboxylic acid from a Acyl chloride?
nucelophilic addition elimination, H₂O
25
What is the type of reaction and conditions neccesary for the formation of a Ester from a Acyl chloride?
nucelophilic addition elimination, Primary alcohol
26
What is the type of reaction and conditions neccesary for the formation of a Amide from a Acyl chloride?
nucleophilic addition elimination, NH₃ or an amine
27
What is the type of reaction and conditions neccesary for the formation of a Ester from a Carboxylic acid?
esterification. , Primary alcohol with concentrated H₂SO₄, distill off product
28
What is the type of reaction and conditions neccesary for the formation of a Alkane from a Carboxylic acid?
decarboxylation, Sodalime (NaOH & CaO)
29
What is the type of reaction and conditions neccesary for the formation of a Alcohol from a Carboxylic acid?
reduction, LiAlH₄
30
What is the type of reaction and conditions neccesary for the formation of a Acyl Chloride from a Carboxylic acid?
reduction, PCl₃ PCl₅ SOCl₂
31
What is the type of reaction and conditions neccesary for the formation of a Amide from a Carboxylic acid?
reduction, NH₃ and heat
32
What is the type of reaction and conditions neccesary for the formation of a Alcohol from a Ester?
hydrolysis, Aqeuous NaOH, heated reflux
33
What is the type of reaction and conditions neccesary for the formation of a Carboxylic acid from a Ester?
hydrolysis, Aqeuous NaOH, heated reflux, then acidify
34
What is the type of reaction and conditions neccesary for the formation of a Amine from a Nitriles?
reduction, LiAlH₄
35
What is the type of reaction and conditions neccesary for the formation of a Carboxylic acid from a Nitriles?
hydrolysis, Aqeuous NaOH, heated reflux, then acidify
36
What is the type of reaction and conditions neccesary for the formation of a Carboxylate salt from a Amides?
hydrolysis, Aqeuous NaOH, heated reflux
37
What is the type of reaction and conditions neccesary for the formation of a Nitrile from a Amides?
dehydration, Heat with P₄O₁₀
38
What is the type of reaction and conditions neccesary for the formation of a Amide from a Amines?
nucelophilic addition elimination, Acyl chloride
39
What is the type of reaction and conditions neccesary for the formation of a Alcohol from a Amines?
nucelophilic addition elimination, HNO₂ (NaNO₂ /HCl in situ)
40
What is the type of reaction and conditions neccesary for the formation of a Nitrobenzene from a Benzene?
nitration electrophilic substitution, Conc H₂SO₄ conc HNO3 (2:1 ratio)
41
What is the type of reaction and conditions neccesary for the formation of a Chlorobenzene from a Benzene?
chlorination electrophilic substitution, Anhydrous AlCl₃ and Cl₂
42
What is the type of reaction and conditions neccesary for the formation of a Bromobenzene from a Benzene?
bromination electrophilic substitution, Anhydrous FeBr₃ and Br₂
43
What is the type of reaction and conditions neccesary for the formation of a Alkyl benzene from a Benzene?
friedel crafts alkylation, Desired chloroalkane and AlCl₃ catalyst
44
What is the type of reaction and conditions neccesary for the formation of a Phenylethanone from a Benzene?
friedel crafts acylation, Desired chlorocarbonyl and AlCl₃ catalyst
45
What is the type of reaction and conditions neccesary for the formation of a Phenylamine from a Nitrobenzene?
reduction, Sn/HCl
46
What is the type of reaction and conditions neccesary for the formation of a Benzenoic acid from a Alkyl benzene?
oxidation, Hot alkaline manganate, then acidify
47
What is the type of reaction and conditions neccesary for the formation of a Phenyl ethanoate from a Phenol?
nucleophilic substitution esterification, Acyl chloride
48
What is the type of reaction and conditions neccesary for the formation of a Bromophenol from a Phenol?
bromination, Br₂
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