1If an acid catalyst (e.g., H2SO4 or HCl) is present,
water adds to alkenes. It adds as H-OH, and the
products are alcohols.
True, Hydration
2Alcohols react with alkenes in the same way that
water does. Like the addition of water, the addition
of an alcohol requires an
acid catalyst.
3The addition of hydrogen to alkenes in the presence
of a catalyst.
Hydrogenation
4Alcohols react with alkenes in the same way that
water does. Like the addition of water, the addition
of an alcohol requires an acid catalyst.
Addition of Alcohols
5The product of the reaction is an
ether
6Addition of halogen will produce
alkylhalide
7hydration of alkene will produce
alcohol
8addition of alcohol will produce
ether
9of double bonds is used
commercially to convert vegetable oils to
margarine and other cooking fats.
Catalytic hydrogenation
10ADDITION OF HALOGEN: ALKENE + HALOGEN =
SINGLE BONDED COMP
11HYDRATION: ALKENE + H20 W/ ACID CATALYST =
ALCOHOL
12ADDITION OF ALC: ALKENE + ALCOHOL =
ETHER (ROR)
13CATALYTIC HYDROGENATION: ALKENE + HYDROGEN W/ CATALYST =
SINGLE BONDS
14If HCl adds to an unsymmetrical alkene like propene,
there are two possible ways it could add. However,
in practice, there is only one major product
according to
Markovnikov's Rule.
15In simplest terms, it states that when a hydrogen halide
(like HCl or HBr) adds to an unsymmetrical alkene, the
hydrogen atom of the halide attaches to the carbon atom of
the alkene that already has more hydrogen atoms attached
to it. Meanwhile, the halogen atom attaches to the other
carbon atom of the alkene.
Markovnikov's Rule
16Think of it like this: the rich get richer. The carbon atom
already "rich" in hydrogen atoms gets the extra hydrogen,
while the other carbon, relatively "poorer" in hydrogen, gets
the halogen. It's all about favoring stability in the resulting
product.
Markovnikov's Rule
17When HX is added to an unsymmetrical alkene, the
hydrogen becomes attached to the carbon with the
most hydrogens attached to it already
18simpleste alkyne
ethyne/acetylene
19substance used for torch used in welding
ethyne
20An ______ has a higher boiling point than an alkene
containing the same number of carbon atoms.
alkyne
21Alkynes, like alkenes, undergo
electrophilic addition reactions
22We will see that the same electrophilic reagents that add to
alkenes also add to alkynes.
Though, alkynes are less reactive than alkenes in electrophilic
addition reactions.
True
23The addition reactions of alkynes, however, have a feature
that alkenes do not have: Because the product of the
addition of an electrophilic reagent to an alkyne is an alkene,
a second electrophilic addition reaction can occur.
True
24If the alkyne is a _____ alkyne, the H+ will add to
the sp carbon bonded to the hydrogen.
terminal
25The product of the second addition reaction is a
_____, a molecule with two halogens on
the same carbon.
geminal dihalide
26Alkynes also undergo the acid-catalyzed
addition of water. The product of the reaction
is an ____.
enol
27___ has a carbon–carbon double bond and an
-OH group bonded to one of the sp2 carbons.
enol
28The enol immediately rearranges to a
ketone
29Hydrogen adds to an alkyne in the presence of a
metal catalyst such as palladium, platinum, or nickel
in the same manner that it adds to an alkene.
True
30The product of the hydrogenation reaction,
therefore, is an .
alkane