1A property that does not affect the chemical identity of a compound
Physical Property
2Can be observed and measured without changing a compounds composition of matter
Physical Property
3Any Substance that has mass and can occupy space
Matter
4Properties of matter that is dependent to the size or amount of the matter
Example : Height, Weight, Temperature, Size, Shape, Volume, etc
Extensive or Extrinsic
5Properties of matter that is independent of the amount and size of the matter; it is constant ;characterizes or defines the matter
Example : Boiling Point, Freezing point, Melting point, Viscosity, and etc
Intensive (Intrinsic)
6forces that holds atom together
Intramolecular Forces
7forces that exist between molecules
Intermolecular Forces
8are dependent on the mass of the molecule
Boiling Points
9the ability to dissolve into a solvent and is dependent on the IMF (Intermolecular Forces)
Solubility
10The strength of the interaction between molecules is also dependent on the overall ____ of the molecule
shape
11Three Types of Intermolecular Forces
1. Hydrogen Bonding (strongest)
2. Dipole-Dipole
3. Van Der Waals or London Dispersion
12is a complex interaction that includes Dipole-Dipole as well as orbital interactions and the transfer of electron density between molecules
Hydrogen Bonding
13is connected to an strongly electronegativity atom like F, O, and N
Hydrogen Bonding
14Hydrogen Bonding is the strongest of the IMFs and range from ______
5-25 kj/mol
15forces arise from the attraction of oppositely charged atoms (other than H) in molecules. These molecules may have a permanent dipole moment. Generally, in organic molecules they result from the presence of C-X bonds where X is more electronegativity to the of C-
Dipole-Dipole
16Present in molecules with partial charges or significant difference in their electronegativity
Dipole-Dipole
17Dipole-Dipole are generally weaker that H-bonding from about ____
5-10 kJ/mol
18forces arise from the movement of electrons within a molecule. This natural motion can produce an uneven distribution of the electrons (polarization of the distribution) resulting in a temporary dipole moment in the molecule. This will induce the movement of electrons in adjacent molecules producing a dipole moment in them
Van Der Waals (London Dispersion)
19Molecules with higher molecular
masses have higher
melting point, boiling point, and density
20- Larger molecular sizes
- Strong London Dispersion forces among
molecules
Higher Molecular Masses
21- Boiling point and density lower than its
straight-chain isomer
Molecules with Branched Chains
22- Have greater surface are in contact with
each other
- Greater attractive force among the
molecules
Straight Chain Isomers
23As a rule, larger molecules have
higher boiling and melting points
Straight Chain Isomers
24Intensive or Intrinsic Property of a
compound; like dissolves like; polar
dissolves polar
Solubility
25If the solvent is polar, like water, then
smaller hydrocarbon component and
more charged hydrogen bonding, and
other polar groups will tend to _______
the solubility.
increase
26The number of Carbons: more carbons
means more of a non-polar/
hydrophobic character, and thus ____
lower solubility in water
27Anything with a charged group
(ammonium, carboxylate, phosphate) is
almost certainly water soluble, unless
it has a ________, in which
case it will most likely be soluble in the
form of micelles, like soap or detergent.
large nonpolar group
28Any functional group that can donate a
hydrogen bond to water (alcohols,
amines) will significantly contribute to
water solubility
29Any functional group that can only
accept a _______ (ketones, aldehydes, ethers) will have a somewhat smaller but still significant
effect on water solubility.
hydrogen bond from water
30Other groups that contribute to polarity
(alkyl, halides, thiols, sulfides) will make
a _______ to water solubility
small contribution