Part 1

30 flashcardsby Alyssa
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1
A property that does not affect the chemical identity of a compound
Physical Property
2
Can be observed and measured without changing a compounds composition of matter
Physical Property
3
Any Substance that has mass and can occupy space
Matter
4
Properties of matter that is dependent to the size or amount of the matter
Example : Height, Weight, Temperature, Size, Shape, Volume, etc
Extensive or Extrinsic
5
Properties of matter that is independent of the amount and size of the matter; it is constant ;characterizes or defines the matter
Example : Boiling Point, Freezing point, Melting point, Viscosity, and etc
Intensive (Intrinsic)
6
forces that holds atom together
Intramolecular Forces
7
forces that exist between molecules
Intermolecular Forces
8
are dependent on the mass of the molecule
Boiling Points
9
the ability to dissolve into a solvent and is dependent on the IMF (Intermolecular Forces)
Solubility
10
The strength of the interaction between molecules is also dependent on the overall ____ of the molecule
shape
11
Three Types of Intermolecular Forces
1. Hydrogen Bonding (strongest)
2. Dipole-Dipole
3. Van Der Waals or London Dispersion
12
is a complex interaction that includes Dipole-Dipole as well as orbital interactions and the transfer of electron density between molecules
Hydrogen Bonding
13
is connected to an strongly electronegativity atom like F, O, and N
Hydrogen Bonding
14
Hydrogen Bonding is the strongest of the IMFs and range from ______
5-25 kj/mol
15
forces arise from the attraction of oppositely charged atoms (other than H) in molecules. These molecules may have a permanent dipole moment. Generally, in organic molecules they result from the presence of C-X bonds where X is more electronegativity to the of C-
Dipole-Dipole
16
Present in molecules with partial charges or significant difference in their electronegativity
Dipole-Dipole
17
Dipole-Dipole are generally weaker that H-bonding from about ____
5-10 kJ/mol
18
forces arise from the movement of electrons within a molecule. This natural motion can produce an uneven distribution of the electrons (polarization of the distribution) resulting in a temporary dipole moment in the molecule. This will induce the movement of electrons in adjacent molecules producing a dipole moment in them
Van Der Waals (London Dispersion)
19
Molecules with higher molecular
masses have higher
melting point, boiling point, and density
20
- Larger molecular sizes
- Strong London Dispersion forces among
molecules
Higher Molecular Masses
21
- Boiling point and density lower than its
straight-chain isomer
Molecules with Branched Chains
22
- Have greater surface are in contact with
each other
- Greater attractive force among the
molecules
Straight Chain Isomers
23
As a rule, larger molecules have
higher boiling and melting points
Straight Chain Isomers
24
Intensive or Intrinsic Property of a
compound; like dissolves like; polar
dissolves polar
Solubility
25
If the solvent is polar, like water, then
smaller hydrocarbon component and
more charged hydrogen bonding, and
other polar groups will tend to _______
the solubility.
increase
26
The number of Carbons: more carbons
means more of a non-polar/
hydrophobic character, and thus ____
lower solubility in water
27
Anything with a charged group
(ammonium, carboxylate, phosphate) is
almost certainly water soluble, unless
it has a ________, in which
case it will most likely be soluble in the
form of micelles, like soap or detergent.
large nonpolar group
28
Any functional group that can donate a
hydrogen bond to water (alcohols,
amines) will significantly contribute to
water solubility
29
Any functional group that can only
accept a _______ (ketones, aldehydes, ethers) will have a somewhat smaller but still significant
effect on water solubility.
hydrogen bond from water
30
Other groups that contribute to polarity
(alkyl, halides, thiols, sulfides) will make
a _______ to water solubility
small contribution
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