1Strongest intermolecular force of attraction, energy ranges from 1-7 kcal /mol
Dipole-Dipole interactions
2Very weka force that exist in all atoms or melecules
Van der Waals
3Orientation effect/alignment effect, exist between dipole-dipole (polar and polar)
Keesom forces
4A polar molecules produces a temporary electric dipole in a non polar molecule
Dipole Induced dipole forces (Debye forces)
5Energy ranges from 1-3 kcal /mole weaker than dipole dipole
debye forces
6Induction effect, combination of dipole and induced dipole
Debye forces
7Weakest intermolecular forces, exist between non polar molecules
London Dispersion forces
8more electrons = stronger forces energy from 0.5 - 1 kcal/mole
London Dispersion Forces
9Dispersion effect with two induced dipoles, nonpolar+ nonpolar
London
10Polar molecules attracted to positive pr negatice charges energy 1-7 kcal/mole
Ion-Dipole forces
11 Attraction induced by close proximity of charged ion to nonpopar molecule
Ion-induced dipole
12Charged atom or molecule + dipole (polar)
Ion dipole
13charged ion + induced dipole (non polar) salt formation
Ion-induced dipole
14Examples: Water, HCI, Ethanol, Phenol, Acetone
Keesom or dipole dipole interactions
15Examples: Methylene chloride, Ethyl Acetate, Ether
Debye forces
16Examples: Carbon tetrachloride, Carbon disulfide, Hexane
London Dispersion
17Examples: Triodid complex, Quaternary ammonium compounds
Ion-Induced dipole
18Special dipole-dipole interaction beteeen H and O, N, or F
Hydrogen Bonding
19Partially positive H is attracted to partially negative O, N, or F of another molecule
Hydrogen Bonding
20Relatively strong force of attraction requires considerable energy to break
Hydrogen Bonding
21Can be both intermolecular and intramolecular
Hydrogen Bonding
22Forces of attrction between non atoms/ molecules in water
Hydrophobic Interactions
23Less known due to lack of bonding with water molecules; water fearing
Hydrophobic Interactions
24Occurs between partially charged ions; relatively strong
Dipole Dipole attraction
25Temporary or induced dipoles: weakest attractions
London Dispersion Attraction
26Types; Ionic, Covalent, Metallic bonds
Intramolecular Forces
27Electrostatic force between oppositely chsrge ions
Ionic or Electrovalent bond
28Involves transfer of electrons ; metal donates, nonmetal accepts
Ionic or Electrovalent bonds
29Formed between atoms with small electronegativity difference
Covalent Bond
30Involves sharing of electrons between two nonmetals
Covalent Bonds