Lesson 2.1

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1
Strongest intermolecular force of attraction, energy ranges from 1-7 kcal /mol
Dipole-Dipole interactions
2
Very weka force that exist in all atoms or melecules
Van der Waals
3
Orientation effect/alignment effect, exist between dipole-dipole (polar and polar)
Keesom forces
4
A polar molecules produces a temporary electric dipole in a non polar molecule
Dipole Induced dipole forces (Debye forces)
5
Energy ranges from 1-3 kcal /mole weaker than dipole dipole
debye forces
6
Induction effect, combination of dipole and induced dipole
Debye forces
7
Weakest intermolecular forces, exist between non polar molecules
London Dispersion forces
8
more electrons = stronger forces energy from 0.5 - 1 kcal/mole
London Dispersion Forces
9
Dispersion effect with two induced dipoles, nonpolar+ nonpolar
London
10
Polar molecules attracted to positive pr negatice charges energy 1-7 kcal/mole
Ion-Dipole forces
11
Attraction induced by close proximity of charged ion to nonpopar molecule
Ion-induced dipole
12
Charged atom or molecule + dipole (polar)
Ion dipole
13
charged ion + induced dipole (non polar) salt formation
Ion-induced dipole
14
Examples: Water, HCI, Ethanol, Phenol, Acetone
Keesom or dipole dipole interactions
15
Examples: Methylene chloride, Ethyl Acetate, Ether
Debye forces
16
Examples: Carbon tetrachloride, Carbon disulfide, Hexane
London Dispersion
17
Examples: Triodid complex, Quaternary ammonium compounds
Ion-Induced dipole
18
Special dipole-dipole interaction beteeen H and O, N, or F
Hydrogen Bonding
19
Partially positive H is attracted to partially negative O, N, or F of another molecule
Hydrogen Bonding
20
Relatively strong force of attraction requires considerable energy to break
Hydrogen Bonding
21
Can be both intermolecular and intramolecular
Hydrogen Bonding
22
Forces of attrction between non atoms/ molecules in water
Hydrophobic Interactions
23
Less known due to lack of bonding with water molecules; water fearing
Hydrophobic Interactions
24
Occurs between partially charged ions; relatively strong
Dipole Dipole attraction
25
Temporary or induced dipoles: weakest attractions
London Dispersion Attraction
26
Types; Ionic, Covalent, Metallic bonds
Intramolecular Forces
27
Electrostatic force between oppositely chsrge ions
Ionic or Electrovalent bond
28
Involves transfer of electrons ; metal donates, nonmetal accepts
Ionic or Electrovalent bonds
29
Formed between atoms with small electronegativity difference
Covalent Bond
30
Involves sharing of electrons between two nonmetals
Covalent Bonds
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