Unit 2 topic 8

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1
What are the common oxidation states of oxygen and hydrogen?
Oxygen: –2, Hydrogen: +1
2
What are the oxidation numbers of the metals in NaOH, MgO, and Al2O3?
Na → +1, Mg → +2, Al → +3
3
What is the oxidation state of oxygen in hydrogen peroxide?
-1
4
What oxidation state is hydrogen in metal hydrides like NaH?
-1
5
What is the oxidation state of Fe in iron(III) chloride?
+3
6
Write the chemical formula of a compound with sulfur at +6 and oxygen at -2.
SO3
7
What is reduction?
Gain of electrons and decrease in oxidation number
8
What is oxidation?
Loss of electrons and increase in oxidation number
9
What is a reducing agent?
Species that donates electrons
10
What is an oxidising agent?
Species that gains electrons
11
What is a redox reaction?
A reaction involving both oxidation and reduction
12
How do you balance Zn and Fe half equations?
Make electron numbers equal, then add: Zn → Zn²⁺ + 2e⁻, 2Fe³⁺ + 2e⁻ → 2Fe²⁺
13
How do you combine Zn and Fe half equations?
Zn + 2Fe³⁺ → Zn²⁺ + 2Fe²⁺
14
Why does ionisation energy decrease down Groups 1 and 2?
More shielding, less nuclear attraction, easier to remove electrons
15
What is the reactivity trend in Group 1?
Increases down the group
16
What is the reactivity trend in Group 2?
Increases down the group
17
What are the products of lithium and water?
Lithium hydroxide and hydrogen
18
What is the equation for sodium and water?
2Na + 2H2O → 2NaOH + H2
19
What is formed when potassium reacts with oxygen?
Potassium oxide
20
What is the equation for lithium and oxygen?
4Li + O2 → 2Li2O
21
What do Group 1 elements form with chlorine?
Metal chlorides (e.g. NaCl)
22
How do Group 2 elements react with oxygen?
2X + O2 → 2XO
23
How do Group 2 elements react with water?
X + 2H2O → X(OH)2 + H2
24
How do Group 2 elements react with chlorine?
X + Cl2 → XCl2
25
What is formed when hydroxides/oxides react with dilute acid?
Salt and water
26
What is the reaction between NaOH and HCl?
NaOH + HCl → NaCl + H2O
27
What is the reaction between Mg(OH)2 and H2SO4?
Mg(OH)2 + H2SO4 → MgSO4 + 2H2O
28
What is the reaction between Li2O and H2SO4?
Li2O + H2SO4 → Li2SO4 + H2O
29
What is the reaction between BaO and HCl?
BaO + 2HCl → BaCl2 + H2O
30
What is produced when Group 1/2 oxides react with water?
Metal hydroxides
31
What is the reaction between CaO and water?
CaO + H2O → Ca(OH)2
32
What is the solubility trend of Group 2 hydroxides?
Increases down the group
33
What is the solubility trend of Group 2 sulfates?
Decreases down the group
34
What is the thermal stability trend of Group 1 and 2 carbonates?
Increases down the group
35
What is the thermal stability trend of Group 1 and 2 nitrates?
Increases down the group
36
Why does thermal stability increase down Groups 1 and 2?
Lower charge density = less distortion of CO3²⁻ or NO3⁻
37
What is the flame test colour for Na⁺?
Orange
38
What is the flame test colour for Li⁺?
Red
39
What is the flame test colour for K⁺?
Lilac
40
What is the flame test colour for Rb⁺?
Red-violet
41
What is the flame test colour for Cs⁺?
Blue-violet
42
What is the flame test colour for Ca²⁺?
Brick red
43
What is the flame test colour for Ba²⁺?
Green
44
What is the flame test colour for Sr²⁺?
Red
45
Why do some cations produce coloured flames?
Electron excitation and photon release
46
How to identify carbonate and hydrogencarbonate ions?
Add acid → CO2 → limewater turns cloudy
47
How to identify sulfate ions?
Add BaCl2 → white precipitate (BaSO4)
48
How to identify ammonium ions?
Add NaOH + warm → ammonia turns red litmus blue
49
What colour is aqueous chlorine?
Colourless
50
What colour is aqueous bromine?
Orange
51
What colour is aqueous iodine?
Brown
52
Why are halogens at different states at room temp?
Different meltingoiling points; trend increases down the group
53
Why does meltingoiling point increase down Group 7?
More intermolecular forces to overcome
54
What is the electronegativity trend in Group 7?
Decreases down the group
55
Why does Group 7 reactivity decrease down the group?
More shielding, harder to gain electrons
56
When does a halogen displacement reaction occur?
More reactive halogen displaces less reactive one
57
What type of reaction is halogen displacement?
Redox
58
Why must halogen B be above A in Group 7 to displace it?
Reactivity increases up the group
59
Which halogens can chlorine displace?
Bromine and iodine
60
Which halogens can't bromine displace?
Chlorine and fluorine
61
Why can't iodine displace chloride or bromide?
It is less reactive
62
Word equation for chlorine and potassium bromide?
Chlorine + potassium bromide → potassium chloride + bromine
63
Symbol equation for bromine and potassium iodide?
Br2 + 2KI → I2 + 2KBr
64
Observation when chlorine is added to KBr?
Colourless → orange
65
Equation for chlorine and sodium?
2Na + Cl2 → 2NaCl
66
What is a disproportionation reaction?
One species is oxidised and reduced in the same reaction
67
Equation for disproportionation of chlorine with NaOH?
2NaOH + Cl2 → NaCl + NaClO + H2O
68
Equation for disproportionation of chlorine with water?
Cl2 + H2O ⇌ 2H⁺ + Cl⁻ + ClO⁻
69
How do NaCl and NaF react with H2SO4?
Not oxidised, form HCl and HF
70
How do bromide ions react with H2SO4?
2Br⁻ + H2SO4 + 2H⁺ → Br2 + SO2 + 2H2O
71
How do iodide ions react with H2SO4?
8I⁻ + H2SO4 + 8H⁺ → 4I2 + H2S + 4H2O
72
How to identify halide ions?
Add HNO3 + AgNO3 → observe precipitate; test solubility with NH3
73
How do hydrogen halides react with water and ammonia?
They donate protons forming acids
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