Qualitative Analysis - 9

30 flashcardsby Hrithik
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1
What is a salt
It is a compound formed when some or all of the hydrogen ions in an acid are replaced by metal ions or ammonium ions
2
What are the 2 types of ions in a salt
Positve (Cation) and Negative (Anion)
3
What are the reagents used to identify cations
Aqueous sodium hydroxide and aqueous ammonia
4
Metal salt + sodium hydroxide gives?
Metal hydroxide + sodium salt
5
Copper (II) chloride + sodium hydroxide gives?
Copper (II) hydroxide + sodium chloride
6
Metal salt + aqueous ammonia gives?
Metal hydroxide + ammonium salt
7
Copper (II) choride + aqueous ammonia gives?
Copper (II) hydroxide + ammonium chloride
8
What is the outcome when testing for ammonium cation with aqueous sodium hydroxide
No precipitate. On warming, pungent gas which turns moist red litmus paper blue is evolved. The gas is ammonia.
9
What is the outcome when testing for aluminium cation with aqueous sodium hydroxide
white precipitate; soluble in excess to form a colourless solution
10
What is the outcome when testing for aluminium cation with aqueous ammonia
white precipitate; insoluble in excess
11
What is the outcome when testing for zinc cation with aqueous sodium hydroxide & aqueous ammonia
white precipitate; soluble in excess to form a colourless solution
12
What is the outcome when testing for calcium cation with aqueous sodium hydroxide
white precipitate; insoluble in excess
13
What is the outcome when testing for calcium cation with aqueous ammonia
no precipitate
14
What is the outcome when testing for Copper(II) cation with aqueous sodium hydroxide
blue precipitate; insoluble in excess
15
What is the outcome when testing for Copper(II) cation with aqueous ammonia
light blue precipitate; soluble in excess to form a dark blue solution
16
What is the outcome when testing for Iron(II) cation with aqueous sodium hydroxide & aqueous ammonia
green precipitate; insoluble in excess
17
What is the outcome when testing for Iron(III) cation with aqueous sodium hydroxide & aqueous ammonia
red-brown precipitate; insoluble in excess
18
What is the test & its result for carbonate anion
Add dilute acid and bubble the gas evolved into limewater. Effervecence is observed and the gas (carbon dioxide) forms white precipitate (calcium carbonate) in the limewater
19
How to write an equation for testing carbonate anions?
Metal carbonate + Dilute Acid → Metal salt + water + carbon dioxide
20
What is the test & its result for chroride anion?
Add dilute nitric acid then add aqueous silver nitrate. White precipitate (silver chloride) is observed
21
How to write an equation for testing chloride anions?
Metal chloride + Silver nitrate → Silver chloride + Metal nitrate
22
What is the test & its result for sulfate anion
Add dilute nitric acid, then add aqueous barium nitrate/aqueous barium chloride. White precipitate (barium sulfate) is observed
23
How to write an equation for testing sulfate anions?
Metal sulfate + Barium chloride → Barium sulfate + Metal chloride
24
What is the test & its result for nitrate anion
add aqueous sodium hydroxide then aluminium foil; warm carefully Test for gas by placing a moist red litmus paper at the mouth of test tube. Effervescence observed. Pungent gas (ammonia) turns moist/damp red litmus paper blue
25
What is a test of ammonia
when it turns moist red litmus paper blue
26
What is a test for carbon dioxide
gives white precipitate with limewater (white ppt dissolves when excess CO2 is bubbled into limewater)
27
What is a test for chlorine
moist blue litmus paper turns red and bleaches white
28
What is a test for hydrogen
extinguishes lighted splint with a ‘pop’ sound
29
What is a test for oxygen
relights / rekindles glowing splint
30
What is a test for sulfur dioxide
turns aqueous acidified potassium manganate(VII) from purple to colourless
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