midterm m4

intensive or extensive properties

properties of matter that
depend on the amount of
the substance present.

intensive or extensive properties


properties of matter that
depend on the matter itself
and do not depend on the
amount of the substance
present

is defined in quantitative terms as the
concentration of solute in a saturated
solution at a certain temperature, and in
a qualitative way, it can be defined as
the spontaneous interaction of two or
more substances to form a
homogeneous molecular dispersion

true or false


UPAC:
-analytical composition of a saturated
solution expressed as a proportion of a
designated solvent in a designated solution

this refers to
solubility at a certain pH measured in a
defined pH- buffered system and
neglects the influence of salt
formation of the buffered system.

BUFFERED SOLUBILITY aka

usually measured in water, this refers to the
solubility of a saturated solution of
compound at the final pH of the solution

solubility of the neutral form of an ionizable
compound, independent from the properties
of solvent

Which is more soluble ? trans (e) isomer or Cis (z)

the higher the solubilty _______

Increasing unsaturation _________ solubility in polar solvents

is an extrinsic material property that can be
influenced by various chemical, physical, or
crystallographic means such as complexation,
particle size, surface properties, solid-state
modification, or solubilization enhancing
formulation strategies

A system in which one or more
substances are homogeneously
mixed or dissolved in another
substance.

is one
in which the solute in
solution is in equilibrium
with the solid phase.

is one
containing the dissolved solute
in a concentration below that
necessary for complete
saturation at a definite
temperature.

one that
contains more of the dissolved solute
than it would normally contain at a
definite temperature, were the
undissolved solute present.

dissolves ionic and polar solutes like ammonia, and some ionic solutes

Can act as cosolvent or intermediate solvent

it can act as intermediate
solvents to bring about miscibility of polar and
nonpolar liquids.

-governed by Henry's Law

It states that the amount of dissolved
gas in a liquid is directly proportional to its
_____________ above the liquid.

what are the FACTORS AFFECTING SOLUBILITY in SOLUBILITY OF GAS IN LIQUID

in the SOLUBILITY OF LIQUID IN LIQUID when liquids mix in all proportions (same polarity)

in the SOLUBILITY OF LIQUID IN LIQUID greatly influenced by temperature (uses semipolar compounds

-solubility of a drug in a mixed solvent in a system is based on the changes in dielectric constant, which may be taken to be the mole fraction of the two solvents.

in SOLUBILITY OF LIQUID IN LIQUID what are the factors that affects solubilty

refers to the reversible movement of a
liquid or a solid in a mixture; governed by
Nernst Law.

The distribution of a solute in two
immiscible liquids depends on the
chemical nature of the solute and the
liquid phases.

It is the minimum pressure which needs to be applied to a solution to
prevent the inward flow of its pure solvent across a semipermeable
membrane

it is also defined as the measure of the tendency of a solution to take in
pure solvent by osmosis

is the maximum
osmotic pressure that could develop in a solution if it were separated
from its pure solvent by a semipermeable membrane.

formula of osmotic pressure

what is the value of R (gas constant value)

Is the decrease of the freezing point of a solvent on the addition of
a non-volatile solute.

temperature at which vapor pressure of solid equals the vapor
pressure of the liquid and at which the solid and liquid are in
equilibrium

formula of freezing point depression

-temperature at which the vapor pressure of the substance equals
atmospheric pressure

formula of boiling point

what is the temp. of water?

temp of bp of water and salt

formula of vapor pressure